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Beilstein J. Org. Chem. 2014, 10, 1017–1022, doi:10.3762/bjoc.10.101
Graphical Abstract
Figure 1: Sansalvamide A (1) and its depsipeptoid analogues (2).
Figure 2: Generic structures of (a) peptide, (b) peptoid, (c) depsipeptide and (d) depsipeptoid.
Figure 3: Structures of six pentadepsipeptoid analogues of San A.
Scheme 1: Retrosynthetic analysis of the cyclic depsipeptoids.
Scheme 2: Synthesis of acyclic depsipeptoids 11a,b.
Scheme 3: Synthesis of macrocycles 2a-f.